Physics of the Solid State
The evolution of the spectral and structural characteristics of La0.98-xLuxEu0.02BO3 orthoborates
Shmurak S. Z/
1, Kedrov V. V.
1, Kiselev A. P
1, Fursova T. N
1, Zver'kova I. I.
1, Khasanov S. S.
1
1Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia
Email: shmurak@issp.ac.ru, kedr@issp.ac.ru, kiselev@issp.ac.ru, fursova@issp.ac.ru, zverkova@issp.ac.ru, khasanov@issp.ac.ru
The structure, IR absorption, luminescence, and luminescence excitation spectra of La0.98-xLuxEu0.02BO3 orthoborates synthesized at 970oC were studied at 0≤ x≤0.98. An increase in x leads to a sequential change of the structural state of the orthoborates. At first, the compound has the aragonite structure. Then, it becomes two-phase and contains the aragonite and vaterite phases. With a further increase in x, the compounds have the vaterite structure, then the vaterite and calcite structure, and, finally, the calcite structure. Correspondence between the structure and spectral characteristics of these compounds was established. Luminescence spectra were investigated at different wavelengths of exciting light. This allowed obtaining information on the structure of a near-surface layer and the bulk of microcrystals of the investigated samples. It is shown that the vaterite phase arises in the bulk of microcrystals of samples that have the aragonite structure. Keywords: phosphors for LEDs, rare earth orthoborates, X-ray diffraction analysis, IR spectroscopy, luminescence spectra.
- C. Mansuy, J.M. Nedelec, C. Dujardin, R. Mahiou. Opt. Mater. 29, 6, 697 (2007)
- G. Blasse, B.C. Grabmaier. Luminescent Materials. Springer--Verlag, Berlin--Heiderberg (1994). 233 p
- Jun Yang, Chunxia Li, Xiaoming Zhang, Zewei Quan, Cuimiao Zhang, Huaiyong Li, Jun Lin. Chem. Eur. J. 14, 14, 4336 (2008)
- Y.H. Zhou, J. Lin, S.B. Wang, H.J. Zhang. Opt. Mater. 20, 1, 13 (2002)
- J. Yang, G. Zhang, L. Wang, Z. You, S. Huang, H. Lian, J. Lin. J. Solid State Chem. 181, 12, 2672 (2008)
- S.Z. Shmurak, A.P. Kiselev, V.V. Sinitsyn, I.M. Shmyt'ko, A.S. Aronin, B.S. Red'kin, E.G. Ponyatovsky. FTT 48, 1, 48 (2006) (in Russian)
- S.Z. Shmurak, A.P. Kiselev, N.V. Klassen, V.V. Sinitsyn, I.M. Shmyt'ko, B.S. Red'kin, S.S. Khasanov. IEEE Trans. Nucl. Sci. 55, 1-3, 1128 (2008)
- S.Z. Shmurak, A.P. Kiselev, D.M. Kurmasheva, B.S. Red'kin, V.V. Sinitsyn. ZhETF 137, 5, 867 (2010) (in Russian)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, I.I. Zver'kova. FTT 55, 2, 336 (2013) (in Russian)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.M. Shmyt'ko. FTT 58, 3, 564 (2016) (in Russian)
- A.A. Mazilkin, O.G. Rybchenko, T.N. Fursova, S.Z. Shmurak, V.V. Kedrov. Mater. Character. 147, 215 (2019)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, I.M. Shmyt'ko. FTT 57, 1, 19 (2015) (in Russian)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.M. Shmyt'ko. FTT 57, 8, 1558 (2015) (in Russian)
- M.A. Elyashevich. Spektroskopiya redkikh zemel'. GITTL, M. (1953). 456 p. (in Russian)
- M.I. Gaiduk, V.F. Zolin, L.S. Gaigerova. Spektry lyuminestsentsii evropiya. Nauka, M. (1974). 195 p. (in Russian)
- J. Holsa. Inorg. Chim. Acta 139, 1-2, 257 (1987)
- E.M. Levin, R.S. Roth, J.B. Martin. Am. Miner. 46, 9-10, 1030 (1961)
- G. Chadeyron, M. El-Ghozzi, R. Mahiou, A. Arbus, C. Cousseins. J. Solid State Chem. 128, 261 (1997)
- D. Santamari a-Perez, O. Gomis, J. Angel Sans, H.M. Ortiz, A. Vegas, D. Errandonea, J. Ruiz-Fuertes, D. Martinez-Garcia, B. Garcia-Domene, Andre L.J. Pereira, F. Javier Manjon, P. Rodri guez-Hernandez, A. Munoz, F. Piccinelli, M. Bettinelli, C. Popescu. J. Phys. Chem. C 118, 4354 (2014)
- Wen Ding, Pan Liang, Zhi-Hong Liu. Mater. Res. Bull. 94, 31 (2017)
- WenDing, Pan Liang, Zhi-Hong Liu. Solid State Sci. 67, 76 (2017)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova. FTT 62, 12, 2110 (2020).(in Russian)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, E.Yu. Postnova. FTT 63, 7, 933 (2021) (in Russian)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, I.I. Zver'kova, E.Yu. Postnova. FTT 63, 10, 1615 (2021) (in Russian)
- R.S. Roth, J.L. Waring, E.M. Levin, Proc. 3rd Conf. Rare Earth Res. Clearwater, Fla. (1964). P. 153
- C. Badan, O. Esenturk, A. Yelmaz. Solid State Sci., 14, 11-12, 1710 (2012)
- I.M. Shmyt'ko, I.N. Kiryakin, G.K. Strukova. FTT 55, 7, 1369 (2013) (in Russian)
- A.P. Kiselev, S.Z. Shmurak, B.S. Red'kin, V.V. Sinitsyn, I.M. Shmyt'ko, E.A. Kudrenko, E.G. Ponyatovsky. FTT 48, 8, 1458 (2006) (in Russian)
- N.I. Steblevskaya, M.I. Belobeletskaya, M.A. Medkov. Zhurn. neorgan. khimii 66, 4, 440 (2021) (in Russian)
- J. Guang, C. Zhang, C. Wang, L. Liu, C. Huang, S. Ding. Cryst. Eng. Commun. 14, 579 (2012)
- J. Zhang, M. Yang, H. Jin, X. Wang, X. Zhao, X. Liu, L. Peng. Mater. Res. Bull. 47, 247 (2012)
- Heng-Wei Wei, Li-Ming Shao, Huan Jiao, Xi-Ping Jing. Opt. Mater. 75, 442 (2018)
- R. Nayar, S. Tamboli, A.K. Sahu, V. Nayar, S.J. Dhoble. J. Fluoresc. 27, 251 (2017)
- S.K. Omanwar, N.S. Savala. Appl. Phys. A 123, 673 (2017)
- C.E. Weir, E.R. Lippincott. J. Res. Natl. Bur. Std.-A. Phys. Chem. 65A, 3, 173 (1961)
- A. Szczeszak, T. Grzyb, St. Lis, R.J. Wiglusz. Dalton Transact. 41, 5824 (2012)
- Ling Li, Shihong Zhou, Siyuan Zhang. Solid State Sci. 10, 1173 (2008)
- A.G. Ryabukhin. Izv. Chelyabinskogo nauch. tsentra 4, 33 (2000) (in Russian)
- W.C. Steele, J.C. Decius. J. Chem. Phys. 25, 6, 1184 (1956)
- Radha Velchuri, B. Vijaya Kumar, V. Rama Devi, G. Prasad, D. Jaya Prakash, M. Vithal. Mater. Res. Bull. 46, 1219 (2011)
- Cansin Badan, Okan Esenturk, Aysen-Yi lmaz. Solid State Sci. 14, 1710 (2012)
- D. Boyer, F. Leroux, G. Bertrand, R. Mahiou. J. Non-Crystalline Solids 306, 110 (2002)
- J.P. Laperches, P. Tarte. Spectrochim. Acta 22, 1201 (1966)
- Jun Yang, Cuimiao Zhang, Lili Wang, Zhiyao Hou, Shanshan Huang, Hongzhou Lian, Jun Lin. J. Solid State Chem. 181, 2672 (2008)
- S.Z. Shmurak, V.V. Kedrov, A.P. Kiselev, T.N. Fursova, O.G. Rybchenko. FTT 59, 1, 1150 (2017) (in Russian).
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