Patterns of formation of electrically conductive properties of oxides of the Magneli series
Ilinskiy A.V.1, Shadrin E.B.1
1Ioffe Institute, St. Petersburg, Russia
Email: shadr.solid@mail.ioffe.ru
The hybridization of vanadium ions and oxygen ions is considered for four vanadium oxides included in the Magneli series: VO, V2O3, VO2, V2O5. Based on the data on hybridization, the details of the structure of the crystal lattice of these oxides are analyzed. For each oxide, the role of electrons not participating in the stabilization of the crystal frame in the process of the semiconductor-metal phase transition was revealed. The complex Mott-Peierls character of the phase transitions in all the listed strongly correlated compounds has been established. It is shown that as the degree of oxidation of the V atom increases, the numerical value of the metallic conductivity of the high-temperature phase naturally decreases and, simultaneously, the temperature of the phase transition from the semiconductor to the metallic state increases. Keywords: phase transitions, Magneli series, electron correlations, hybridization of atomic orbitals.
- P.K. Sekhar, D.D. Graf, O. Ojelere, T.K. Saha, M.A. Riheen, S. Mathur. J. Electrochem. Soc. 167, 027548-1 (2020)
- L.A. Nosikova, A.E. Baranchikov, A.D. Yapryntsev, O.S. Ivanova, M.A. Teplonogova, V.K. Ivanov. Zhurn. neorgan. khimii 65, 4, 467 (2020). (in Russian)
- A.V. Ilinskiy, E.B. Shadrin. FTT 62, 8, 1284 (2020). (in Russian). DOI: doi.org/10.21883/FTT.2020.08.49616.081]
- N.S. Akhmetov. Obschaya i neorganicheskaya khimiya. Vyssh. shk., M. (2001). (in Russian)
- W. Kohn, L.J. Sham. Phys. Rev. 140, 4A, A1133--A1138 (1965). DOI: 10.1103/PhysRev.140.A1133
- M. Gatti, F. Bruneval, V. Olevano, L. Reining. Phys. Rev. 99, 266402-1 (2007)
- A. Boum. Kvantovaya mekhanika: osnovy i prilozheniya. Mir, M. (1990). 720 p. (in Russian)
- Neorganicheskaya khimiya / Eds. Yu.D. Tretyakov. Akademiya, M. (2007). V. 3. 352 p. (in Russian)
- T.D. Nguen, A.I. Zanko, D.A. Golosov, S.M. Zavadsky, S.N. Melnikov. Dokl. BGUIR 19, 3, 22 (2021). (in Russian). DOI: http://dx.doi.org/10.35596/1729-7648-2021-19-3-22-30
- S.V. Vonsovsky, M.I. Katsnelson. Kvantovaya fizika tverdogo tela. Nauka, M., (1983), 336 p. (in Russian)
- A.V. Ilinskiy, E.B. Shadrin. FTT 64, 10, 1552 (2022). (in Russian)
- W. Bruckner, H. Opperman, W. Reichelt, E.I. Terukov, F.A. Tschudnovskii. Vanadiumdioxide. Akademie-Verlag, Berlin (1983). 252 p
- A.V. Ilinskiy, E.B. Shadrin. FTT 64, 6, 702 (2022). (in Russian)
- J.B. Goodenough. Czech. J. Phys. B 17, 304 (1967)
- J.B. Goodenough. In: Progress in Inorganic Chemistry / Ed. H. Reiss. Pergamon Press, Oxford (1971). V. 5. P. 145
- M.G. Baronsky. Dis.kand. fiz.-mat. nauk. Novosibirsk, (2020). 162 p. (in Russian)
- F.J. Morin. Phys. Rev. Lett. 3, 34 (1959)
- I.C. Austin. Phil. Mag. 7, 961 (1962)
- W.W. Warren, G.A. Miranda, W.G. Clark. Butt. Am. Phys. Soc. 12, 1117 (1967)
- A.V. Ilinskiy, O.E. Kvashenkina, E.B. Shadrin. FTP 46, 4, 439 (2012). (in Russian)
- A.S. Davydov. Kvantovaya mekhanika. Nauka, M., (1973). 596 p. (in Russian)
- M.W. Park, Y.S. Lim, Y.M. Sung, D.J. Kwak, J.S. Lee. Acta Phys. Polonica A 129, 4, 875 (2016)
- D. Mukherjee, A. Dey, A.C.M. Esther, N. Sridhara, D.R. Kumar, A. Rajendra, A.K. Sharmab, A.K. Mukhopadhyay. RSC Adv. 8, 30966 (2018). DOI: 10.1039/c8ra04957b]
- P.S. Bell, M.H. Lewi. Phys. Status Solidi 7, 431 (1971)
- N. Mott. Metal--Insulator Transitions. Taylor \& Francis Ltd. (1974). 216 p. ISBN 978-0-85066-079-1]
- A.B. Migdal. UFN 147, 10, 210 (1985). (in Russian)
- M. Gatti, F. Bruneval, V. Olevano, L. Reining. Phys. Rev. 99, 266402-1 (2007)
- G. Lantz. Ultrafast electron dynamics in Mott materials. These de doctorat. Paris (2015). 145 p
- Ch. Prameela1, M. Anjaiah, K. Krishna Murthy \& K. Indian Pure Appl. Phys. 51, 563 (2013)
- R.E.F. Silva, I.V. Blinov, A.N. Rubtsov, O. Smirnova, M. Ivanov. Nature Photon. 12, 266 (2018)
- I.A. Sluchinskaya. Osnovy materialovedeniya i tekhnologii poluprovodnikov. M. (2002). 376 p. (in Russian)
Подсчитывается количество просмотров абстрактов ("html" на диаграммах) и полных версий статей ("pdf"). Просмотры с одинаковых IP-адресов засчитываются, если происходят с интервалом не менее 2-х часов.
Дата начала обработки статистических данных - 27 января 2016 г.