Technical Physics
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The influence of temperature on electrophysical characteristics of carbon--containing polymer composites
The influence of temperature on the electrophysical characteristics of polymer composites based on a matrix of ethylene vinyl acetate filled with carbon black (CB) is investigated. It is established that the most noticeable transformation of the temperature dependences of the resistivity rho(T) after the first heating-cooling cycle occurs in composite samples saturated with peroxide. Saturation of the composite with peroxide and the crosslinking of macromolecules leads to the N-shaped character of the dependence rho(T). The occurrence of hysteresis rho(T) and its character indicate that in the studied composites, the process of crystallization of the polymer matrix has significantly less effect on the destruction of the conductive mesh formed as a result of agglomeration of CB particles compared with the processes accompanying melting. Keywords: polymer composites, carbon black, electrical conductivity, temperature dependence.
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