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Molecular Photonics of 3,3'-diethyl-9-methylthiacarbocyanine Monomers and Dimeric Complexes with Cucurbit[8]uril
Russian version
DOI: 10.21883/EOS.2022.05.54436.3-22
Fedotova T. V.1, Zakharova G. V.1, Chibisov A. K.1
1Photochemistry Center, FSRC "Crystallography and Photonics", Russian Academy of Sciences, Moscow, Russia
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A comparative study of the spectral-luminescent and spectral-kinetic properties of 3,3'-diethyl-9-methylthiacarbocyanine (MTCC) and 3,3'-diethylthiacarbocyanine (TCC) and their complexes with cucurbit[8]uril in aqueous solution was carried out. Dimeric complexes of TCC with cucurbit[8]uril consist of trans-isomers and exhibit only delayed fluorescence while dimeric complexes of MTCC consist of cis-isomers and exhibit both delayed fluorescence and phosphorescence in water. The dimeric complexes of MTCC and TCC with cucurbit[8]uril participate in the electron phototransfer reaction where the dimeric complex of MTCC exhibits a greater ability to enter into photooxidation reactions. Keywords: polymethine dyes, trans-cis isomerization, cucurbiturils, absorption, fluorescence, triplet-triplet absorption, electron phototransfer.
  1. A.K. Chibisov, S.V. Shvedov, H. Gorner. J. Photochem. Photobiology A: Chemistry, 141 (1), 39 (2001). DOI: 10.1016/S1010-6030(01)00426-9
  2. D. Guillaumont, S. Nakamura. Dyes and Pigments, 46 (2), 85 (2000). DOI: 101016/S0143-7208(00)00030-9
  3. K.G. Vladimirova, A.Ya. Freidzon, A.A. Bagaturyants, G.V. Zakharova, A.K. Chibisov, M.V. Alfimov. Khimiya vysokikh energiy, 42 (4), 317 (2008) (in Russian). [K.G. Vladimirova, A.Y. Freidzon, A.A. Bagatur'yants et al. High Energy Chem., 42 (4), 275 (2008). DOI: 10.1134/S0018143908040061]
  4. G.V. Zakharova, V.G. Avakyan, A.K. Chibisov, M.V. Alfimov. High Energy Chem., 51 (3), 195 (2017). DOI: 10.1134/S0018143917030158
  5. P.M. Henrichs, S. Gross. J. Am. Chem. Soc., 98 (23), 7169 (1976)
  6. V.I. Yuzhakov. Russ. Chem. Rev., 48 (11), 2007 (1979). DOI: 10.1070/RC1979v048n11ABEH002430
  7. A.K. Chibisov. High Energy Chem., 41 (3), 200 (2007). DOI: 10.1134/S0018143907030071
  8. B.I. Shapiro. Russ. Chem. Rev., 75 (5), 433 (2006). DOI: 10.1070/RC2006v075n05ABEH001208
  9. A.K. Chibisov, T.D. Slavnova, H. Gorner. Nanotechnologies in Russia, 3 (1), 19 (2008)
  10. L.S. Atabekyan, D.A. Voznyak, G.V. Zakharova, A.K. Chibisov. High Energy Chem., 42 (6), 454 (2008). DOI: 10.1134/S0018143908060064
  11. A.K. Chibisov, G.V. Zakharova. Photochem. Photobiol. Sci., 11 (6), 893 (2012). DOI: 10.1039/C1PP05273J
  12. A.K. Chibisov, T.D. Slavnova, G.V. Zakharova, H. Gorner. High Energy Chem., 41 (5), 344 (2007). DOI: 10.1134/S0018143907050074
  13. G.V. Zakharova, A.K. Chibisov. High Energy Chem., 47 (6), 322 (2013). DOI: 10.1134/S001814391306012X
  14. L.S. Atabekyan, V.G. Avakyan, A.K. Chibisov. High Energy Chem., 45 (2), 123 (2011). DOI: 10.1134/S0018143911020020
  15. G.V. Zakharova, V.G. Avakyan, V.P. Markelov, N.L. Svyatoslavskii, T.A. Svyatoslavskaya, A.K. Chibisov. High Energy Chem., 49 (6), 407 (2015). DOI: 10.1134/S001814391506017X]
  16. G.V. Zakharova, V.G. Avakyan, A.K. Chibisov, M.V. Alfimov. High Energy Chem., 51 (3), 195 (2017). DOI: 10.1134/S0018143917030158
  17. T.V. Fedotova, V.N. Gutrov, G.V. Zakharova, A.K. Chibisov, M.V. Alfimov. High Energy Chem., 53 (1), 22 (2019). DOI: 10.1134/S0018143919010041
  18. G.V. Zakharova, T.V. Fedotova, V.N. Gutrov, A.K. Chibisov, M.V. Alfimov. High Energy Chem., 53 (6), 449 (2019). DOI: 10.1134/S0018143919060158
  19. G.V. Zakharova, V.N. Gutrov, M.V. Alfimov et al. High Energy Chem., 51 (5), 404 (2017). DOI: 10.1134/S0018143917050162
  20. A.K. Chibisov, G.V. Zakharova, H. Gorner. Phys. Chem. Chem. Phys., 1 (7), 1455 (1999). DOI: 10.1039/A809354G
  21. A.K. Chibisov, G.V. Zakharova, H. Gorner. Phys. Chem. Chem. Phys., 3 (1), 44 (2001). DOI: 10.1039/B005683I
  22. L.S. Atabekyan, A.K. Chibisov. High Energy Chem., 41 (2), 91 (2007). DOI: 10.1134/S0018143907020075
  23. W. West, S. Pearce. J. Phys. Chem., 69 (6), 1894 (1965)
  24. T.D. Slavnova, A.K. Chibisov, H. Gorner. J. Phys. Chem. A, 106 (46), 10985 (2002). DOI: 10.1021/jp020210t
  25. M.V. Alfimov, A.K. Chibisov, G.V. Zakharova, T.V. Fedotova, V.G. Plotnikov. Izv. vuzov. Fizika, 63 (8), 63 (2020) (in Russian). DOI: 10.17223/00213411/63/8/63 [M.V. Alfimov, A.K. Chibisov, G.V. Zakharova et al. Russ. Phys. J., 63 (8), 1363 (2020). DOI: 10.1007/s11182-020-02179-0]

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