Luminescence photomodulation of nanospheres with CdSe/ZnS quantum dots in polymer films
Karpach P. V.1, Vasilyuk G. T.1, Venidiktova O. V.2, Barachevsky V. A.2, Tuktarov A. R.3, Maskevich S. A.4, Artemiev M. V.5
1Yanka Kupala Grodno State University, Grodno, Belarus
2Photochemistry Center, FSRC "Crystallography and Photonics", Russian Academy of Sciences, Moscow, Russia
3Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia
4Belarusian State University, ISEI BSU, Minsk, Belarus
5Research Institute for Physical Chemical Problems of the Belarussian State University, Minsk, Belarus
Email: pavel_karpach@mail.ru, vasilyuk@grsu.by, wolga.photonics@inbox.ru, barva@photonics.ru, tuktarovar@gmail.com, sergei.maskevich@gmail.com, m_artemyev@yahoo.com

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The results of studies of the spectral-kinetic (absorption and fluorescent) characteristics of the polymer nanospheres created by us (containing luminescent inorganic CdSe/ZnS quantum dots and photochromic diarylethene molecules) incorporated into a polymer film are presented. A reversible modulation of the fluorescence intensity of quantum dots, caused by the photoisomerization of diarylethene molecules, was found. It is shown that nanospheres in polymer matrices exhibit higher efficiencies of both photoinduced modulation of QD radiation and Forster resonance energy transfer (FRET) from QDs to the cyclic isomer of DAE as compared to solutions. The results can be used, for example, to create luminescent photocontrolled panels based on films containing fluorescent nanoparticles. Keywords: photochromism, fluorescence, quantum dot, Forster resonance energy transfer, polymer nanospheres, polymer films
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