Physics of the Solid State
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Ferroelectric properties of lead zirconate titanate thin films obtained by RF magnetron sputtering near the morphotropic phase boundary
Staritsyn M. V. 1, Fedoseev M. L. 1, Kiselev D. A. 2, Kaptelov E. Yu. 3, Pronin I. P. 3, Senkevich S. V. 3, Pronin V. P. 4
1Central Research Institute of Structural Materials Prometey, National Research Centre Kurchatov Institute, St. Petersburg, Russia
2National University of Science and Technology MISiS, Moscow, Russia
3Ioffe Institute, St. Petersburg, Russia
4Herzen State Pedagogical University of Russia, St. Petersburg, Russia
Email: ms_145@mail.ru, fedoseevml@hotmail.com, dm.kiselev@gmail.com, kaptelov@mail.ioffe.ru, Petrovich@mail.ioffe.ru, Senkevichsv@mail.ioffe.ru, pronin.v.p@yandex.ru

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An experimental study of the crystal structure and ferroelectric properties of <110>-textured lead zirconate titanate films with a fine variation in their composition (with a change in the elemental ratio of zirconium and titanium atoms within 1.5%) near the morphotropic phase boundary revealed jump-like changes in the pseudocubic lattice parameter, dielectric permittivity and residual polarization. It is assumed that the observed anomalies correspond to a morphotropic transition from a rhombohedral to a mixture of tetragonal and monoclinic phases. Keywords: fine composition variation, phase state, piezoresponse force microscopy, abnormal dielectric and piezoelectric properties.
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