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Charge transfer excitons in HTSC cuprates and nickelates
Russian version
DOI: 10.61011/EOS.2023.04.56356.70-22
Moskvin A. S. 1,2
1Ural Federal University after the first President of Russia B.N. Yeltsin, Yekaterinburg, Russia
2M.N. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
Email: alexander.moskvin@urfu.ru
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An analysis of the optical properties of compounds based on 3d-elements provides valuable information about the electronic structure of the ground state and low-energy excitations. Thus, we show that the analysis of charge-transfer d-d excitons in the dielectric antiferromagnetic phase of cuprates and metastable low-energy electron-hole EH dimers being a result of their evolution after electron-lattice relaxation, turns out to be very fruitful not only for describing linear and nonlinear optical properties and photoinduced effects, but also to develop a promising model of charge triplets to describe the low-energy electronic structure and T-x phase diagrams of active CuO2 planes in cuprates of the T-La2CuO4 or T-Nd2CuO4 type, as well as NiO2-planes in nickelates of the RNiO2 type, and their evolution with changes in the main energy parameters. Keywords: cuprates, nickelates, charge-transfer excitons, electron-hole dimers, charge triplets. DOI: 10.61011/EOS.2023.04.56356.70-22
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