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Infra-red spectroscopy of reflection-absorbance with account for thin surface layers: the theoty and experiment
Russian version
Michailov A.V. 1, Povolotskiy A. V.1, Kuzmin V.L.2
1St. Petersburg State University, St. Petersburg, Russia
2Peter the Great Saint-Petersburg Polytechnic University, St. Petersburg, Russia
Email: kuzmin_vl@mail.ru
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The description of the reflectance-absorbance spectra for the light reflecting from the plane boundary between absorbing liquid phase and the gaseous one is developed accounting a thin anisotropic absorbing interfacial layer. The surface contributions are shown being described in terms of four integral parameters of the permittivity profiles universal respectively of the incidence angle and the type of profile. The results of performed studies of angular dependency of the reflectance-absorbance spectra in the infra red region for the lipid on the water- gas interface are in a fair agreement numerically with the model considered. Keywords: Plane interface boundary, reflectance-absorbance, permittivity.
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