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Polar properties of spherulite thin films of lead zirconate-titanate obtained by high-temperature annealing from an amorphous phase
Russian version
Valeeva A. R. 1, Pronin I. P. 1, Kaptelov E. Yu. 1, Senkevich S. V. 1, Starytsin M. V. 1, Kiselev D. A. 1, Nemov S. A.1
1Ioffe Institute, St. Petersburg, Russia
Email: Petrrovich@mail.ioffe.ru
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The effect of the microstructure (block size and new intrablock boundaries) of spherulite thin films of lead zirconate titanate on the magnitude of the internal field and self-polarization is studied. The films, whose composition corresponded to the region of the morphotropic phase boundary, were formed by a two-stage method of high-frequency magnetron sputtering. It is shown that the magnitude of the radial-lateral tensile mechanical stresses changes as the size of the blocks increases, leading to a redistribution of the negative space charge (electrons) in the volume of the thin film. A possible contribution to the formation of self-polarization of the space charge of oxygen vacancies caused by their directed diffusion is considered. Keywords: thin films of lead zirconate-titanate, spherulite microstructure, lateral mechanical stresses, internal field, self-polarization, directed diffusion of oxygen vacancies.
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