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Phase composition, structure and transport characteristics of ZrO2-Sc2O3 solid solution crystals additionally doped with Yb2O3
Russian version
DOI: 10.21883/PSS.2022.13.52071.01s
Borik M. A.1, Korableva G. M.1,2, Kulebyakin A. V.1, Kuritsyna I. E.1,2, Lomonova E. E.1, Milovich F. O.1,3, Myzina V. A.1, Tabachkova N. Yu.1,3
1Prokhorov General Physics Institute of the Russian Academy of Sciences, Moscow, Russia
2Osipyan Institute of Solid State Physics RAS, Chernogolovka, Russia
3National University of Science and Technology MISiS, Moscow, Russia
Email: kulebyakin@lst.gpi.ru
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The effect of the co-doped Yb2O3 on the transport characteristics and stabilization of the cubic phase in solid solutions based on ZrO2-Sc2O3 has been carried out. (ZrO2)1-x-y(Sc2O3)x(Yb2O3)y solid solution crystals, where (x=0.07-0.09; y=0.01-0.03), were grown by directional crystallization of the melt in a cold crucible. It is shown that crystals with a cubic fluorite structure were obtained at a total concentration of stabilizing oxides Sc2O3 and Yb2O3 above 10 mol%. At a fixed concentration of Sc2O3, crystals with a total concentration of stabilizing oxides of 10 mol.%, which have the structure of a pseudocubic t''-phase, have the maximum conductivity. Crystals with a total concentration of stabilizing oxides of 10 mol, having a pseudocubic t''-phase structure, at a fixed concentration of Sc2O3, have the maximum conductivity. It is shown that an increase in the Yb2O3 concentration in the field of cubic solid solutions leads to a decrease in the conductivity of the crystals. The (ZrO2)0.9(Sc2O3)0.09(Yb2O3)0.01 crystals have the maximum conductivity in the entire temperature range. Keywords: Crystal growth from melt, zirconium dioxide, solid electrolytes.
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