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Electrical conductivity and structural conditionality of ion transfer in langasite La3Ga5SiO14:Mn
Russian version
DOI: 10.21883/PSS.2022.12.54382.446
Sorokin N. I. 1, Golovina T. G.1, Konstantinova A. F.1
1Shubnikov Institute of Crystallography “Crystallography and Photonics”, Russian Academy of Sciences, Moscow, Russia
Email: nsorokin1@yandex.ru
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The temperature dependence of the static electrical conductivity sigmadc(T) of a single crystal of lanthanum gallium silicate (langasite) La3Ga5SiO14 activated with an impurity of Mn (1000 ppm) has been studied by impedance spectroscopy. Impedance measurements of La3Ga5SiO14 (sp. gr. P321, Z=1) were carried out along crystallographic axes a (double symmetry axis) and c (triple symmetry axis). It was found that the values of sigma|| a are significantly higher than the electrical conductivity sigma|| c, the anisotropy of the electrical conductivity is sigma|| a/sigma|| c=170 at 773 K. The activation energy of electrotransport is Esigma=0.75±0.05 and 1.09±0.02 eV along the a and c axes, respectively. The electrical conductivity mechanism has an ionic nature and an impurity character; oxygen vacancies VOoo are the most probable current carriers. Keywords: lanthanum gallium silicate, langasite family, single crystal, electrical conductivity, anisotropy.
  1. E.L. Belokoneva, M.A. Simonov, A.V. Butashin, B.V. Mill, N.V. Belov. DAN SSSR 255, 1099 (1980) (in Russian)
  2. A.A. Kaminsky, S.E. Sarkisov, B.V. Mill, G.G. Khodzhabagyan. DAN SSSR 264, 93 (1982) (in Russian)
  3. I.A. Andreyev, M.F. Dubovnik. Pisma ZhETF 10, 487 (1984) (in Russian)
  4. B.V. Mill, Yu.V. Pisarevsky. Proc. 2000 IEEE Inter. Frequency Control Symp. (2000). P. 133
  5. I.A. Andreyev. ZHTF 76, 80 (2006)
  6. Company "Fomos-Materialy". https://newpiezo.com
  7. E.N. Domoroshchina, G.M. Kuzmicheva, V.B. Rybakov, A.B. Dubovsky, E.A. Tyunina, S.Yu. Stepanov. Perspektiv. materialy 4, 17 (2004) (in Russian)
  8. E.L. Belokoneva, N.V. Belov. DAN SSSR 260, 1363 (1981) (in Russian)
  9. B.V. Mill, A.V. Butashin, G.G. Khodzhabagyan, E.L. Belokoneva, N.V. Belov. DAN SSSR 264, 1385 (1982) (in Russian)
  10. T. Iwataki, H. Ohsato, K. Tanaka, H. Morikoshi, J. Sato, K. Kawasaki. J. Eur. Ceram. Soc. 21, 1409 (2001)
  11. A. Lidiard. Ionnaya provodimost kristallov. Izd-vo IL, M. (1962). 222 p. (in Russian)
  12. I.S. Rez, Yu.M. Poplavko. Dielektriki. Radio i svyaz, M. (1989) 287 p. (in Russian)
  13. K.A. Kaldybayev, A.F. Konstantinova, Z.B. Perekalina. Girotropiya odnoosnykh pogloshchayushchikh kristallov. Izd-vo ISPIN, M. (2000). 300 p. (in Russian)
  14. G.M. Kuzmicheva, O. Zakharko, E.A. Tyunina, V.B. Rybakov, E.N. Domoroshchina, A.B. Dubovsky. Kristallografiya 53, 1046 (2008) (in Russian)
  15. F.A. Kroger. The chemistry of inperfect crystals. North-Holland, Amsterdam (1964). 1039 p
  16. N.L. Sizova, T.G. Golovina, A.F. Konstantinova, A.P. Dudka. Kristallografiya 66, 910 (2021) (in Russian)
  17. A.B. Dubovsky, E.A. Tyunina, E.N. Domoroshchina, G.M. Kuzmicheva, V.B. Rybakov. Neorgan. materialy 44, 601 (2008) (in Russian)
  18. A.M. Aronova, G.V. Berezhkova, A.V. Butashin, A.A. Kaminsky. Kristallografiya 35, 933 (1990) (in Russian)
  19. O.M. Kugaenko, E.S. Torshina, V.S. Petrakov, O.A. Buzanov, S.A. Sakharov. Izv. vuzov. Materialy elektron. tekhniki 3, 174 (2014)
  20. O.M. Kugaenko, S.S. Uvarova, S.A. Krylov, B.R. Senatulin, V.S. Petrakov, O.A. Buzanov, V.N. Yegorov, S.A. Sakharov. Izv. RAN. Ser. fiz. 76, 1406 (2012) (in Russian)
  21. N.I. Sorokin. FTT bf 62, 1897 (2020) (in Russian)
  22. O.A. Buzanov, N.S. Kozlova, E.V. Zabelina, A.P. Kozlova, N.A. Siminel. Izv. vuzov. Materialy elektron. tekhniki 1, 14 (2010)
  23. E.N. Domoroshchina, A.B. Dubovsky, G.M. Kuzmicheva, G.V. Semenkovitch. Neorgan. materialy 41, 1378 (2005) (in Russian)
  24. I.M. Anfimov, O.A. Buzanov, A.P. Kozlova, N.S. Kozlova. Izv. vuzov. Materialy elektron. tekhniki 2, 21 (2011)
  25. S.P.S. Badwal. Solid State Ionics 52, 23 (1992)
  26. N.I. Sorokin. Elektrokhimiya 36, 357 (2000) (in Russian)
  27. M. Filal, C. Petot, M. Mokchah, C. Chateau, J.L. Carpentier. Solid State Ionics 80, 27 (1995)
  28. A.K. Ivanov-Shic, N.I. Sorokin, P.P. Fedorov, B.P. Sobolev. FTT 25, 1748 (1983)
  29. L.I. Ivleva, N.S. Kozlova, E.V. Zabelina. Kristallografiya 52, 344 (2007) (in Russian)
  30. F. Yu, X. Zhao, L. Pan, F. Li, D. Yuan, S. Zhang. J. Phys. D 43, 165402 (2020)
  31. D.A. Spassky, N.S. Kozlova, A.P. Kozlova, E.V. Zabelina, O.A. Buzanov. FTT 61, 441 (2019) (in Russian)
  32. M. Kitaura, K. Mochizuki, Y. Inabe, M. Itoh, H. Nakagawa, S. Oishi. Phys. Rev. B. 69, 115120 (2004)
  33. R.D. Shannon. Acta Cryst. A. 32, 751 (1976)
  34. A.K. Ivanov-Shic, I.V. Murin. Ionika tverdogo tela. Izd-vo SPbGU, SPb (2010). Vol. 2. 1000 p. (in Russian)
  35. N.I. Sorokin. Elektrokhimiya 44, 1111 (2008) (in Russian)

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