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Crystal structure and thermodynamic properties of germanate CuEu2Ge2O8
Copper-europium germanate CuEu2Ge2O8 was obtained from the initial CuO, Eu2O3 and GeO2 oxides using solid-phase synthesis by annealing in air in the temperature range of 1223-1273 K. Its crystal structure was determined (space group Cm). The influence of temperature on high-temperature heat capacity of the synthesized germanate was studied by the differential scanning calorimetry method. It was found that the dependence of heat capacity on temperature has an extreme value related to a phase transition. The thermodynamic properties were calculated based on the experimental data about heat capacity. Keywords: copper-europium germanate, solid-phase synthesis, crystal structure, thermodynamic properties.
- L.N. Demyanets, A.N. Lobachev, G.A. Yemelyanenko. Germanaty redkozemelnykh elementov. Nauka, M. (1980). 152 p. (in Russian)
- I.A. Bondar, N.V. Vinogradova, L.N. Demyanets, Zh.A. Yezhova, V.V. Ilyukhin, V.Yu. Kara-Ushanov, L.N. Komissarova, E.V. Lazarevski, B.N. Litvin, P.P. Melnikov, D.A. Murashov, V.P. Orlovsky, K.K. Palkina, M.A. Petrova, I.A. Rozanov, N.N. Chudinova, A.A. Fotiyev. Soyedineniya redkozemelnykh elementov. Silikaty, germanaty, fosfaty, arsenaty, vanadaty. Nauka, M. (1983). 288 p. (in Russian)
- E.A. Juarez-Arellano, J. Campa-Molina, S. Ulloa-Godinez. Mater. Res. Soc. Symp. Proc. 848, FF6.15.1 (2005)
- V.M. Denisov, S.A. Istomin, O.I. Podkopayev, N.V. Belousova, E.A. Pastukhov, L.I. Serebryakova, T.O. Kvasova. Germaniy, yego soyedineniya i splavy. UrO RAN, Ekaterinburg (2002). 600 p. (in Russian)
- H. Yamane, R. Tinimura, T. Yamada, J. Takahashi, M. Shimada. J. Solid State Chem. 179, 289 (2006)
- U. Lambert, W. Eysel. Powder. Diff. 1, 2, 45 (1986)
- U. Lambert, W. Eysel. Powder. Diff. 1, 3, 256 (1986)
- H. Cho, M. Kratochvilova, H. Sim, K.-Y. Choi, C.H. Kim, C. Paulsen, M. Avdeev, D.C. Peets, Y. Jo, S. Lee, Y. Noda, M.J. Lawler, J.-G. Park. Phys. Rev. B 95, 144404-1 (2017)
- H. Cho, M. Kratochvilova, N. Lee, H. Sim, J.-G. Park. Phys. Rev. B 96, 224427-1 (2017)
- J.A. Campa, E. Gutierez-Puebla, M.A. Monge, C.R. Valero, J. Rivas, I. Rasines. J. Solid State Chem. 120, 2, 254 (1995)
- E.J. Baran, C. Cascales. J. Raman. Spectrosc. 30, 77 (1999)
- L.T. Denisova, M.S. Molokeyev, Yu.F. Kargin, L.A. Irtyugo, N.V. Belousova, V.M. Denisov. ZhNKh 66, 12, 1700 (2021) (in Russian)
- Bruker AXS TOPAS V4: General profile and structure analysis softwere for powder diffraction data. User's munual. Bruker AXS Karsruhe, Germany (2008)
- L.T. Denisova, L.A. Irtyugo, Yu.F. Kargin, V.V. Beletsky, V.M. Denisov. Neorgan. materialy 53, 1, 71 (2017) (in Russian)
- C.G. Maier, K.K. Kelley. J. Am. Chem. Soc. 54, 8, 3234 (1932)
- L.T. Denisova, L.A. Irtyugo, Yu.F. Kargin, V.V. Beletsky, N.V. Belousova, V.M. Denisov. Neorgan. materialy 54, 2, 181 (2018) (in Russian)
- J. Leitner, P. Chuchvalec, D. Sedmidubsky. Thermochim. Acta 395, 27 (2003)
- J. Laitner, D. Sedmidubsky, B. Douvsova. Thermochim. Acta 345, 49 (2000)
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