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The reason for the revision of conjugated polymers Raman bands attribution
Prosanov I. Yu.
1, Sidelnikov A. A.1, Volodin V. A.2,3
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk State University, Novosibirsk, Russia
2Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk State University, Novosibirsk, Russia
Email: prosanov@mail.ru, sidelnikovsolid.nsc.ru
The bands similar to D and G-bands of carbonaceous materials and bands of conjugated polymers were observed in polyvinyl alcohol (PVA)-iodine complex Raman spectra. It contradicts to their common attribution because PVA has no C=C bonds. Based on this result it is supposed that treatment of sp2 hybridized carbon structures Raman behavior should be revised. Keywords: polyvinyl alcohol, PVA-iodine complex, hybrid interpolymeric complexes, conjugated polymers. DOI: 10.61011/EOS.2023.02.55795.3658-22
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