Optics and Spectroscopy
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Spectral and emission properties of the water-soluble cationic Pd(II) complex with Nile red
Feoktistova V. A.1, Baichurin R. I.
1, Novikova T. A.
1, Plekhanov A. Yu.
2, Puzyk M. V.
1
1Herzen State Pedagogical University of Russia, St. Petersburg, Russia
2 Smorodintsev Research Institute of Influenza (a Russian Ministry of Health federal institution), St. Petersburg, Russia
2 Smorodintsev Research Institute of Influenza (a Russian Ministry of Health federal institution), St. Petersburg, Russia
Email: vik.feok.108@mail.ru, ruslanio85@mail.ru, tamaranovikova52@mail.ru, puzyk@mail.ru
Procedure for the synthesis of a cationic water-soluble Pd(II) complex with 9-diethylamino-5H-benzo[a]phenoxazin-5-one (Nile red) [PdEnNR]OAc (where En - is ethylenediamine, NR - is deprotonated Nile red, OAc - is outer-sphere acetate-ion) is developed. The positive solvatochromism of the luminescent properties of the Pd(II) complex has been established. The influence of DNA on the spectral-luminescent properties of [PdEnNR]OAc was studied. Intercalation of the complex into DNA in water was found. Keywords: cyclometallated Pd(II) complex, Nile red, luminescence, intercalation of the Pd(II) complex in DNA. DOI: 10.61011/EOS.2023.02.55796.4480-22
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