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The manifestation of surface and size effects in the magnetic properties of ε-Fe2O3 nanoparticles. (Brief overview)
Russian version
DOI: 10.21883/PSS.2023.06.56105.12H
Balaev D. A.1, Dubrovsky A. A.1, Knyazev Yu.V.1, Semenov S. V.1, Kirillov V. L.2, Martianov O. N.2
1Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
2Boreskov Institute of Catalysis, Siberian Branch of RAS, Novosibirsk, Russia
Email: dabalaev@iph.krasn.ru
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Polymorphic modification of iron oxide, known as ε-Fe2O3, exists only in the form of nanoparticles with characteristic sizes up to several tens of nanometers. Particles of these sizes exhibit a large coercive force, about 20 kOe at room temperature. In the temperature range of 80-150 K, a magnetic transition occurs in ε-Fe2O3, accompanied by a sharp decrease in the coercive force. At the same time, there are significant differences in the magnetic behavior of "large" (~20 nm) particles and ultra-small particles (up to 6 nm). A number of experimental facts indicate the manifestation of size effects that lead to a change in the magnetic structure in particles of these sizes. In addition, a surface effect is also manifested for such particles - a significant contribution to the magnetic behavior is governed by surface magnetic anisotropy. In this paper, a brief review of the manifestation of these size and surface effects in the magnetic properties of ε-Fe2O3 nanoparticles is carried out. Keywords: iron oxide ε-Fe2O3, nanoparticles, size effect, surface magnetic anisotropy.
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