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Light Fullerene Poly-nitro-adduct C60(NO2)18(OH)2
Arshinov M. Yu1, Subbotin D. I.
1, Shan Yanchen1, Keskinov V. A.
2, Charykov N. A.1, Alikin M. B.1, Kulenova N. A.
2, Semenov K. N.
3, Yurev G. O.3, German V. P.1, Keskinova M. V.
2, Letenko D. G.
4
1Saint-Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia
2Veritas Center, D. Serikbayev East Kazakhstan State Technical University, Ust-Kamenogorsk, Kazakhstan
3Pavlov First St. Petersburg State Medical University, St. Petersburg, Russia
4 Saint Petersburg State University of Architecture and Civil Engineering, Saint Petersburg, Russia
2Veritas Center, D. Serikbayev East Kazakhstan State Technical University, Ust-Kamenogorsk, Kazakhstan
3Pavlov First St. Petersburg State Medical University, St. Petersburg, Russia
4 Saint Petersburg State University of Architecture and Civil Engineering, Saint Petersburg, Russia
Email: arshinovmu@gmail.com, subbotin1987@mail.ru, keskinov@mail.ru, 3007kulenova53@gmail.com, semenov1986@yandex.ru, glebbi407@mail.ru, ilao2010@mail.ru, keskinova88@mail.ru, dletenko@mail.ru
By direct heterogeneous non-catalytic nitration of fullerene C60 with a mixture of concentrated nitric and sulfuric acids was synthesized poly-nitro-adduct C60(NO2)18(OH)2. Excess of nitric acid from the reaction mixture was removed by treatment with hydrogen peroxide, and sulfuric acid - by dialysis from aqueous solutions. The identification of the poly-nitro-adduct was carried out using the following methods: elemental C-H-N analysis, energy dispersion spectral microanalysis, infrared spectroscopy, and nuclear magnetic resonance, high-performance liquid chromatography, thermo-gravimetric analysis. Keywords: poly-nitro-adduct, fullerene C60, synthesis, identification.
- A.I. Vogel, Textbook of practical organic chemistry, 3nd ed. (London Group Ltd., London, 1957)
- J. Clayden, N. Greeves, S. Warren, Organic chemistry, 2nd ed. (Oxford University Press, U.K., 2012)
- L.N. Sidorov, M.A. Yurovskaya, A.Ya. Borshchevskii, I.V. Trushkov, I.N. Ioffe, Fullereny (Ekzamen, M., 2005) (in Russian)
- N.Ya. Dem'yanov, Zh. Russ. Fiz.-Khim. O-va., 33 (4), 275 (1901) (in Russian)
- R.E. Ivanov, M.N. Zharkov, S.G. Zlotin, Dokl. Chem., 500, 209 (2021). DOI: 10.1134/S0012500821100037
- L.Y. Chiang, J.B. Bhonsle, L. Wang, S.F. Shu, T.M. Chang, J.R. Hwu, Tetrahedron, 52, 4963 (1996). DOI: 10.1016/0040-4020(96)00104-4
- L.Y. Chiang, R.B. Upasani, J.W. Swirczewski, J. Am. Chem. Soc., 114, 10154 (1992). DOI: 10.1021/ja00052a010
- V.V. Sharoyko, S.V. Ageev, A.A. Meshcheriakov, N.E. Podolsky, J.P. Vallejo, L. Lugo, I.T. Rakipov, A.V. Petrov, A.V. Ivanova, N.A. Charykov, K.N. Semenov, J. Mol. Liq., 344, 117658 (2021). DOI: 10.1016/j.molliq.2021.117658
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