Optimization of chemical composition and structure of the photocatalyst of ZnO-SnO2-Fe2O3 system
Gavrilova D. A.1,2, Gavrilova M. A.1,2, Khomutinnikova L. L.1, Evstropiev S. K.1,2,3, Meshkovskii I. K.1
1ITMO University, St. Petersburg, Russia
2Saint-Petersburg State Institute of Technology (Technical University), St. Petersburg, Russia
3Vavilov State Optical Institute, St. Petersburg, Russia
Email: amonobel@yandex.ru
The work carried out studies to optimize the chemical composition and structure of the photocatalyst of the ZnO-SnO2-Fe2O3 system for sensor and medical applications. Photocatalytic materials were synthesized by liquid polymer-salt method and their structure and chemical composition were studied by XRD and SEM analysis and optical and luminescence spectroscopy. Obtained composites are composed from hexagonal ZnO crystals, tetragonal SnO2 crystals and ZnSn2O4 spinel. The band gap values of prepared materials are 3.17-3.24 eV. The kinetic dependencies of the adsorption of organic diazo dye Chicago Sky Blue from solutions on the composite surfaces are successfully described by kinetic equations of as pseudo-first so as pseudo-second orders. The kinetics of photocatalytic dye decomposition under UV and visible irradiations is successfully described by kinetic equation of pseudo-first order. It was found that Ag addition allows to remarkably enhance adsorptive and photocatalytic properties of SnO-SnO2-Fe2O3 materials. Keywords: nanocrystals, heterostructure, photocatalysis, adsorption.
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