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Transferability of crystal-field parameters for rare-earth ions in Y₂SiO₅ tested by Zeeman Spectroscopy ^*

DOI: 10.21883/FTT.2019.05.47586.17F

Переводная версия: 10.1134/S1063783419050123

Jobbitt N.L.¹, Patchett S.J.¹, Alizadeh Y.¹, Reid M.F.¹, Wells J.-P.R.¹, Horvath S.P.^1,2, Longdell J.J.^2,3, Ferrier A.^3,4, Goldner P.⁴

¹School of Physical and Chemical Sciences, University of Canterbury, PB, Christchurch, New Zealand

School of Physical and Chemical Sciences, University of Canterbury, Christchurch, New Zealand

²Department of Physics, University of Otago, Dunedin, New Zealand

³Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, Paris, France

⁴Faculte des Sciences et Ingenierie, Sorbonne Universite, Paris, France Faculté des Sciences et Ingénierie, Sorbonne Université, Paris, France

Email: mike.reid@canterbury.ac.nz

Выставление онлайн: 19 апреля 2019 г.

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Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C₁ point-group symmetry sites in Er³⁺ : Y₂SiO₅ may be transferred to other ions. The two crystallographic six- and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.

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